Selective catalytic reduction of NOx by ethanol over combined catalyst Ag/Al2O3-Cu/Al2O3 in excess oxygen

被引:0
|
作者
Zhang, CB [1 ]
Shi, XY [1 ]
He, H [1 ]
机构
[1] Chinese Acad Sci, Ecoenvironm Sci Res Ctr, Beijing 100085, Peoples R China
关键词
silver; copper; alumina; supported catalyst; combined catalyst; nitrogen oxide; selective catalytic reduction; ethanol;
D O I
暂无
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The selective catalytic reduction of NO, by ethanol was studied over Ag/Al2O3 and Cu/Al2O3 catalysts with different metal loadings. The 4 % Ag/Al2O3 and 10 % Cu/Al2O3 showed the highest NO, reduction activity, respectively. The 4 % Ag/Al2O3 catalyst showed excellent NOx to N-2 activity but produced a large amount of CO during the reduction process. The 10% Cu/Al2O3 catalyst was not so active in the reduction of NO, by ethanol, but it was very effective for removing the CO. The combined catalyst formed by direct placing 10 % Cu/Al2O3 after 4 % Ag/Al2O3 showed a similar activity for the NOx reduction and could also remove the CO efficiently. In addition, the concentration of ethanol and aldehyde was also greatly reduced in the effluent gas.
引用
收藏
页码:645 / 649
页数:5
相关论文
共 14 条
  • [1] A review of the selective reduction of NOx, with hydrocarbons under lean-burn conditions with non-zeolitic oxide and platinum group metal catalysts
    Burch, R
    Breen, JP
    Meunier, FC
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2002, 39 (04) : 283 - 303
  • [2] Comparison of Ag/Al2O3 and Ag-ZSM5 catalysts for the selective reduction of NO with propylene in the presence of oxygen
    Furusawa, T
    Lefferts, L
    Seshan, K
    Aika, K
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2003, 42 (01) : 25 - 34
  • [3] Novel Pd promoted Ag/Al2O3 catalyst for the selective reduction of NOx
    He, H
    Wang, J
    Feng, QC
    Yu, YB
    Yoshida, K
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2003, 46 (02) : 365 - 370
  • [4] REMOVAL OF NITROGEN MONOXIDE FROM EXHAUST GASES THROUGH NOVEL CATALYTIC PROCESSES
    Iwamoto, Masakazu
    Hamada, Hideaki
    [J]. CATALYSIS TODAY, 1991, 10 (01) : 57 - 71
  • [5] Role of organic nitro compounds in selective reduction of NOx with ethanol over different supported silver catalysts
    Kameoka, S
    Chafik, T
    Ukisu, Y
    Miyadera, T
    [J]. CATALYSIS LETTERS, 1998, 51 (1-2) : 11 - 14
  • [6] Study of the lean NOx reduction with C3H6 in the presence of water over silver/alumina catalysts prepared from inverse microemulsions
    Martínez-Arias, A
    Fernández-García, M
    Iglesias-Juez, A
    Anderson, JA
    Conesa, JC
    Soria, J
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2000, 28 (01) : 29 - 41
  • [7] Mechanistic aspects of the selective reduction of NO by propene over alumina and silver-alumina catalysts
    Meunier, FC
    Breen, JP
    Zuzaniuk, V
    Olsson, M
    Ross, JRH
    [J]. JOURNAL OF CATALYSIS, 1999, 187 (02) : 493 - 505
  • [8] Selective reduction of NOx by ethanol on catalysts composed of Ag/Al2O3 and Cu/TiO2 without formation of harmful by-products
    Miyadera, T
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 1998, 16 (02) : 155 - 164
  • [9] Shi XY, 2005, CHINESE J CATAL, V26, P69
  • [10] Catalytic performance of Ag-Al2O3 catalyst for the selective catalytic reduction of NO by higher hydrocarbons
    Shimizu, K
    Satsuma, A
    Hattori, T
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2000, 25 (04) : 239 - 247