Electrochemically crosslinked surface-grafted PVK polymer brushes as a hole transport layer for organic photovoltaics

被引：39

作者：

Tria, Maria Celeste ^{[2
,3
]}

Liao, Kang-Shyang ^{[1
]}

Alley, Nigel ^{[1
,4
]}

Curran, Seamus ^{[1
]}

Advincula, Rigoberto ^{[2
,3
]}

机构：

[1] Univ Houston, Dept Phys, Inst NanoEnergy, Houston, TX 77204 USA

[2] Univ Houston, Dept Chem, Houston, TX 77204 USA

[3] Univ Houston, Dept Chem & Biomol Engn, Houston, TX 77204 USA

[4] Dublin City Univ, Sch Phys Sci, Dublin 9, Ireland

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2011年 / 21卷 / 28期

基金：

美国国家科学基金会;

关键词：

LIGHT-EMITTING-DIODES; SOLAR-CELLS; CARBAZOLE; POLY(N-VINYLCARBAZOLE); ELECTRODEPOSITION; INTERFACE; PATHWAYS;

D O I：

10.1039/c1jm11068c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electrochemically crosslinked surface-grafted poly(N-vinylcarbazole) (PVK) brushes as hole transport layers (HTLs) on a photovoltaic device have been demonstrated using SI-RAFT polymerization. Comparable performance to PEDOT: PSS/P3HT: PCBM based devices was achieved. A main advantage is strong adhesion to ITO with a possible long-term stability against acid dopants and oxygen.

引用

页码：10261 / 10264

页数：4

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