Syntheses and crystal structures of triorganotin(IV) complexes based on mixed ligands of 2,4,5-trifluoro-3-methoxybenzoic acid and 4,4′-bipy

被引：7
|
作者：
Ma, Chun-Lin [1 ]
Han, Ya-Wen
Zhang, Ru-Fen
机构：
[1] Liaocheng Univ, Dept Chem, Liaocheng 252059, Peoples R China
[2] Taishan Univ, Tai An 271021, Peoples R China
来源：
STRUCTURAL CHEMISTRY | 2007年 / 18卷 / 05期
关键词：
2,4,5-trifluoro-3-methoxybenzoic acid; 4,4 '-Bipy; organotin(IV); 2D network;
D O I：
10.1007/s11224-007-9177-7
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Four new complexes have been synthesized based on the 2,4,5-trifluoro-3-methoxybenzoic acid and 4,4 '-bipy of the type [R3Sn(OOCC6HF3OCH3)](2)center dot(4,4'-bpy). All complexes were characterized by elemental, IR, H-1, C-13 and Sn-119 NMR spectra analyses. Complexes 1 and 4 were also characterized by X-ray crystallography. Crystal structures of 1 and 4 show that the coordination number of tin atom is five and the 2D network is connected by intermolecular C-H center dot center dot center dot O interactions.
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页码：573 / 578
页数：6
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