Extending the coordination chemistry of 1,3,5-triaza-7-phosphaadamantane (PTA) to cobalt centers: First examples of Co-PTA complexes and of a metal complex with the PTA oxide ligand

被引：43

作者：

Jaremko, Lukasz ^{[1
,2
]}

Kirillov, Alexander M. ^{[1
]}

Smolenski, Piotr ^{[1
]}

Lis, Tadeusz ^{[2
]}

Pombeiro, Armando J. L. ^{[1
]}

机构：

[1] Univ Tecn Lisboa, Ctr Quim Estrutural, Inst Super Tecn, P-1049001 Lisbon, Portugal

[2] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 08期

关键词：

D O I：

10.1021/ic702373b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Water-soluble Co-III and Co-II complexes with P- or N-coordinated PTA or PTA oxide ligands, respectively, have been prepared and fully characterized, constituting the first examples of cobalt compounds bearing PTA or any ligand with a cage-like PTA core, the latter complex providing also the first PTA oxide coordination to a metal center.

引用

页码：2922 / 2924

页数：3

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