Copper(I) Nitrate π-Complexes: Synthesis and Structure of [Cu(CH2=CH-CH2-CN)(NO3)]

被引：0

作者：

Filinchuk, Ya. E. ^{[1
]}

Oliinik, V. V. ^{[1
]}

Davydov, V. N. ^{[1
]}

机构：

[1] Franko State Univ, UA-290005 Lvov, Ukraine

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 1997年 / 23卷 / 11期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Crystals of the CuNO(3) pi-complex with allyl cyanide are obtained by ac electrochemical synthesis, and their structure is determined [DARCh diffractometer, MoK(alpha) radiation, R = 0.022 for 902 independent reflections, F >= 4 sigma(F)]. The pi-complex crystallizes in space group P2(1)/b, a = 10.137(2), b = 9.671(2), c = 6.848(1) angstrom, alpha = 101.75(2)degrees, Z = 4. The copper coordination polyhedron is a distorted tetrahedron formed by two O atoms, and N atom of the cyano group, and a C=C bond. The structure of the compound is compared with those of previously studied CuNO(3) pi-complexes.

引用

页码：791 / 793

页数：3

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