In recent years, graduate employment became a hot topic of community concerns. "Entrepreneurship to create jobs", it is an effective way to solve the employment of university students that is to promote and support the undergraduate students who start their own business. With the Internet age, information technology is developing rapidly. The e-commerce has many features, such as open, global, low-cost, interactive, etc. So e-commerce becomes the first choice of many business students. By analyzing the types of students business mode, this paper is exploring the feasibility of business students through e-commerce. Analysis of various educational methods about the current universities entrepreneurship education. Then find out the inadequacies in order to improve it. Of course, there is the risk of entrepreneurship. By search a amounts of data and analysis of survey results, this paper presents a solution to entrepreneurial risk. To help students understand the process and risk of e-commerce entrepreneurs. That gives undergraduate students to open up more job opportunities.