Synthesis and characterization of a new organic-inorganic hybrid polyphosphazene polymer

被引：7
|
作者：
Huang XiaoBin [1 ]
Yin Lin [1 ]
Tang XiaoZhen [1 ]
机构：
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Technol, Shanghai 200240, Peoples R China
来源：
SCIENCE IN CHINA SERIES B-CHEMISTRY | 2008年 / 51卷 / 01期
关键词：
polyphosphazene; allylamine; phenol; mixed-substituent;
D O I：
10.1007/s11426-007-0120-y
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new organic-inorganic hybrid polyphosphazene polymer was synthesized via sequential nucleophilic substitution using allylamine and phenol. The polymer was characterized by FTIR, H-1-NMR, and P-31-NMR spectra. The thermal properties were studied by DSC and TGA. It was found that the polymer has good thermal stability. Char yields of the polymer reaches to 48.6% at 800 degrees C. The high char yield makes it possible in theory for the polymer to be used as flame retardant. By cross linking, the thermal stability of the polymer could be improved further.
引用
收藏
页码：46 / 50
页数：5
相关论文
共 50 条
  • [1] Synthesis and characterization of a new organic-inorganic hybrid polyphosphazene polymer
    XiaoBin Huang
    Lin Yin
    XiaoZhen Tang
    [J]. Science in China Series B: Chemistry, 2008, 51 : 46 - 50
  • [2] Synthesis and characterization of a new organic-inorganic hybrid polyphosphazene polymer
    HUANG XiaoBin
    [J]. Science China Chemistry, 2008, (01) : 46 - 50
  • [3] Synthesis and characterization of a new family of hybrid organic-inorganic glasses
    Trejo-Duran, M
    Martínez-Richa, A
    Vera-Graziano, R
    Castaño, VM
    [J]. MATERIALS RESEARCH INNOVATIONS, 2005, 9 (03) : 72 - 73
  • [4] Synthesis and characterization of organic-inorganic hybrid microspheres
    Podkoscielna, Beata
    Sobiesiak, Magdalena
    [J]. ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2016, 22 (4-6): : 631 - 638
  • [5] Synthesis and Characterization of PAC-PDMDAAC Organic-Inorganic Hybrid Polymer Flocculants
    Jiang, Shao-jie
    Li, Xiao-en
    Feng, Xin-rui
    [J]. ACTA POLYMERICA SINICA, 2014, (04) : 466 - 472
  • [6] Synthesis and characterization of a new organic-inorganic hybrid mesoporous basic catalyst
    Wang Hong-Su
    Wu Shu-Jie
    Shao Yan-Qiu
    Xu Ling
    Song Ke
    Xu Hai-Yan
    Kan Qiu-Bin
    [J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2007, 28 (08): : 1528 - 1531
  • [7] Synthesis and characterization of a new organic-inorganic hybrid material based on antimony
    Tlili, Imen
    Essalhi, Rim
    Mousdi, George
    Abdelbaky, Mohammed S. M.
    Chaabouni, Slaheddine
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2022, 1251
  • [8] Synthesis and characterization of organic-inorganic interpenetrating polymer networks
    Jackson, CL
    Bauer, BJ
    [J]. ANTEC'97 - PLASTICS SAVING PLANET EARTH, CONFERENCE PROCEEDINGS, VOLS 1 - 3, 1997, : 1908 - 1909
  • [9] Synthesis and characterization of polystyrene/nanosilica organic-inorganic hybrid
    Yuan Wang-Zhang
    Mao, Peng
    Yu Qiu-Ming
    Tang Ben-Zhong
    Qiang, Zheng
    [J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2006, 22 (06) : 797 - 802
  • [10] Synthesis and Characterization of Polystyrene/Nanosilica Organic-Inorganic Hybrid
    YUAN Wang-zhang~ 1
    2. National Engineering Research Center for Compounding and Modification of Polymer Materials
    3. Department of Chemistry
    [J]. Chemical Research in Chinese Universities, 2006, (06) : 797 - 802
12345