Facile AlCl3-Promoted Catalytic Beckmann Rearrangement of Ketoximes

被引：24

作者：

Liu, Li-Feng ^{[1
]}

Liu, Hua ^{[1
]}

Pi, Hong-Jun ^{[1
]}

Yang, Shuo ^{[1
]}

Yao, Min ^{[1
]}

Du, Wenting ^{[1
]}

Deng, Wei-Ping ^{[1
]}

机构：

[1] E China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China

来源：

SYNTHETIC COMMUNICATIONS | 2011年 / 41卷 / 04期

关键词：

Aluminum chloride; Beckmann rearrangement; ketoxime; CYCLOHEXANONE OXIME; EPSILON-CAPROLACTAM; SUPERCRITICAL WATER; IONIC LIQUIDS; AMIDES; CONVERSION; LACTAMS; ACID; INHIBITORS; TRIFLATE;

D O I：

10.1080/00397911003629416

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[image omitted] Aluminum chloride, an inexpensive and commercially available Lewis acid traditionally employed for Beckmann rearrangement with stoichiometric amounts, has been now found to smoothly promote the Beckmann rearrangement of various ketoximes to the corresponding amides (up to 99% of yield) with 10mol% catalyst loading in anhydrous acetonitrile under reflux temperature.

引用

页码：553 / 560

页数：8

共 50 条

[1] Facile AlCl3-Promoted Catalytic Beckmann Rearrangement of Ketoximes (vol 41, pg 553, 2011)
Liu, Li-Feng
Liu, Hua
Pi, Hong-Jun
Yang, Shuo
Yao, Min
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Deng, Wei-Ping
[J]. SYNTHETIC COMMUNICATIONS, 2011, 41 (22) : 3433 - 3433
[2] CLAY CATALYZED FACILE BECKMANN REARRANGEMENT OF KETOXIMES
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[J]. SYNTHETIC COMMUNICATIONS, 1990, 20 (20) : 3253 - 3258
[3] Catalytic Beckmann rearrangement of ketoximes in ionic liquids
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