2,2-Dichloro-1,3-bis(trimethylsilyl)-1,3-diaza-2-silacyclopentane

被引：2
|
作者：
Boehme, Uwe [1 ]
Bendrath, Franziska [1 ]
Guenther, Betty [1 ]
机构：
[1] Tech Univ Bergakad Freiberg, Inst Anorgan Chem, D-09596 Freiberg, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2007年 / 63卷 / o631-o632期
关键词：
Coordination reactions - Metal ions - Molecular structure;
D O I：
10.1107/S0108270107045969
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the title compound, C8H22Cl2N2Si3, the central Si atom is tetrahedrally coordinated by two Cl and two N atoms in a molecule that has crystallographically imposed C-2 symmetry. Comparison is made with the isomorphous structure having titanium instead of silicon at the central position in the diazacyclopentane ring.
引用
收藏
页码：O631 / O632
页数：2
相关论文
共 50 条
  • [1] Cyclic silylhydroxylamines and 1,3-diaza-2-silacyclopentane - Lithium derivatives and reactions
    Diedrich, F
    Ebker, C
    Klingebiel, U
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2001, 168 : 577 - 580
  • [2] Cyclic Silylhydroxylamines and 1,3-Diaza-2-Silacyclopentane - Lithium Derivatives and Reactions
    Diedrich, Friedhelm
    Ebker, Christina
    Klingebiel, Uwe
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2001, 169 (01) : 253 - 256
  • [3] The surprising reactions of 1,3-di-tert-butyl-2,2-dichloro-1,3-diaza-2-germa-4-cyclopentene
    West, Robert
    Moser, Daniel F.
    Guzei, Ilia A.
    Lee, Gyu-Hwan
    Naka, Akinobu
    Li, Wenjian
    Zabula, Alexander
    Bukalov, Sergei
    Leites, Larissa
    ORGANOMETALLICS, 2006, 25 (11) : 2709 - 2711
  • [4] 1,3-DIPOLAR CYCLOADDITION OF 2,2-DICHLORO-1,3-DIPHENYLAZIRIDINE WITH DIMETHYL ACETYLENEDICARBOXYLATE
    DEKIMPE, N
    SULMON, P
    DEBUYCK, L
    VERHE, R
    SCHAMP, N
    DECLERCQ, JP
    VANMEERSSCHE, M
    JOURNAL OF CHEMICAL RESEARCH-S, 1984, (03): : 82 - 83
  • [5] Molecular structure and conformations of 2,2-di-tert-butyl-1,3-diaza-2-silacyclopentane:: Gas electron diffraction and quantum chemical calculations
    Oberhammer, H
    Girichev, GV
    Giricheva, NI
    Krasnov, AV
    Klingebiel, U
    INORGANIC CHEMISTRY, 2004, 43 (11) : 3537 - 3542
  • [6] Configurations of 1,3-bis(aryl)-1,3-diaza-2-thiaallenes in the crystal state
    Bagryanskaya, IY
    Gatilov, YV
    Zibarev, AV
    MENDELEEV COMMUNICATIONS, 1999, (04) : 157 - 158
  • [7] SYNTHESIS OF 2,2-DICHLORO-1,3-DIMETHYL-BICYCLO[1,1,1]PENTANE
    GRIGOREV, AE
    TARAKANOVA, AV
    MILVITSKAYA, EM
    PISANOV, NV
    MOROZOVA, NM
    PLATE, AF
    VESTNIK MOSKOVSKOGO UNIVERSITETA SERIYA 2 KHIMIYA, 1980, 21 (05): : 498 - 503
  • [8] INACTIVATION OF CATHEPSIN DEUTERIUM BY DITHIOPHOSGENE AND BY 2,2-DICHLORO-1,3-DITHIACYCLOBUTANONE
    RAKITZIS, ET
    MALLIOPOULOU, TB
    BIOCHEMICAL JOURNAL, 1976, 153 (03) : 737 - 739
  • [9] 1,3-BIS(TRIMETHYLSILYL)PROPENE AS 1,3-PROPENE AND 3,3-PROPENE DIANION SYNTHONS - REACTIONS OF 2-ARYL-1,3-BIS(TRIMETHYLSILYL)PROPENES WITH ELECTROPHILES
    WENG, WW
    LUH, TY
    JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (09): : 2760 - 2762
  • [10] SELECTIVE PREPARATION OF "1,3-BIS(TRIMETHYLSILYL)-1-PROPENYL, "1,3-BIS(TRIMETHYLSILYL)-2-PROPENYL, AND 3-TRIMETHYLSILYL-1,2-PROPADIENYL FUNCTIONAL-GROUPS
    ATSUMI, K
    KUWAJIMA, I
    TETRAHEDRON LETTERS, 1977, (23) : 2001 - 2004
12345