Ambient dinitrogen electrocatalytic reduction for ammonia synthesis

被引：61

作者：

Chen, Aling ^{[1
]}

Xia, Bao Yu ^{[1
]}

机构：

[1] Huazhong Univ Sci & Technol, Key Lab Mat Chem Energy Convers & Storage, Hubei Key Lab Mat Chem & Serv Failure, Sch Chem & Chem Engn,Wuhan Natl Lab Optoelect,Min, 1037 Luoyu Rd, Wuhan 430074, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2019年 / 7卷 / 41期

基金：

中国国家自然科学基金;

关键词：

NITROGEN REDUCTION; ELECTROCHEMICAL SYNTHESIS; HIGH SELECTIVITY; N-2; FIXATION; CATALYTIC-ACTIVITY; LOW-TEMPERATURE; NANOSHEETS; CARBON; NH3; ELECTROSYNTHESIS;

D O I：

10.1039/c9ta05505c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ammonia holds considerable significance for modern human community and the natural world. Ambient electrochemical NH3 synthesis powered by renewable energy rather than the energy-intensive Haber-Bosch process is promising for the future development of a sustainable society. Developing highly efficient electrocatalysts with low overpotential, considerable selectivity, and faradaic efficiency is, therefore, necessary, yet formidably challenging. In this review, various advanced technologies and available electrocatalytic materials for ammonia synthesis under mild conditions are briefly reviewed based on both experimental and theoretical studies. Three categories, namely, noble-metal-, nonnoble-metal-, and carbon-based materials, have been mainly reviewed, and certain inspiring strategies in improving the efficiency have been proposed to promote the future development of electrochemical ammonia synthesis. Finally, conclusions and perspectives are provided for the continuous innovation of highly effective electrocatalysis in ambient N-2 reduction and NH3 synthesis for a sustainable society.

引用

页码：23416 / 23431

页数：16

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