Methane conversion using carbon dioxide as an oxidizing agent: A review

被引：82
|
作者：
Yabe, Tomohiro [1 ]
Sekine, Yasushi [1 ]
机构：
[1] Waseda Univ, Res Inst Sci & Engn, Shinjuku Ku, 3-4-1 Okubo, Tokyo 1698555, Japan
来源：
FUEL PROCESSING TECHNOLOGY | 2018年 / 181卷
基金：
日本学术振兴会;
关键词：
Catalytic methane conversion; Syngas production; Endothermic reaction; C-2; hydrocarbon; Electric field; TEMPERATURE HYDROGEN-PRODUCTION; DIELECTRIC-BARRIER DISCHARGES; DENSITY-FUNCTIONAL THEORY; C-2; HYDROCARBONS; BIMETALLIC CATALYSTS; SYNTHESIS GAS; NI/SIO2; CATALYST; NI CATALYSTS; SUPPORTED NI; SELECTIVE CONVERSION;
D O I：
10.1016/j.fuproc.2018.09.014
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Recent trends on the direct conversion of methane, employing carbon dioxide as an oxidizing agent are reviewed. While oxidation using molecular oxygen involves the sequential oxidation of various intermediates to generate carbon dioxide and exhibits low selectivity for the desired products, methane activation using carbon dioxide as an oxidant eliminates this sequential oxidation and has considerable promise. In this context, supported metal catalysts can promote the dry reforming of methane, and structured oxide catalysts have been found to enable methane coupling to C-2 products, using carbon dioxide as the oxidizing agent. This review also summarizes recent research regarding the use of nonconventional processes for methane activation in conjunction with carbon dioxide.
引用
收藏
页码：187 / 198
页数：12
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