Construction of a chiral zinc-camphorate framework for enantioselective separation

被引：4

作者：

Zhu, Chengfeng ^{[1
]}

Wang, Hongzhao ^{[1
]}

Mu, Yongfei ^{[1
]}

Zhang, Ziwei ^{[1
]}

Cheng, Lanjun ^{[1
]}

Li, Tianfu ^{[1
]}

Fu, Yanming ^{[1
]}

Wu, Xiang ^{[1
]}

Li, Yougui ^{[1
]}

机构：

[1] Hefei Univ Technol, Sch Chem & Chem Engn, Anhui Prov Key Lab Adv Catalyt Mat & React Engn, Hefei 230009, Anhui, Peoples R China

来源：

DALTON TRANSACTIONS | 2022年 / 51卷 / 25期

关键词：

METAL-ORGANIC FRAMEWORKS; AMINO-ACID; RECOGNITION; ENANTIOMERS; ADSORPTION;

D O I：

10.1039/d2dt01221a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A chiral metal-organic framework (CMOF) with open chiral channels and multiple recognition sites is constructed from camphoric acid and a dipyridyl ligand. It can act as an efficient chiral solid adsorbent, capable of separating a variety of racemic alcohols and epoxides with excellent enantioselectivities.

引用

页码：9627 / 9631

页数：5

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