Discrete Iridamacrocycle Formation via C-H Activation of an N-Heterocycle

被引：10
|
作者：
Yu, Wei-Bin [1 ]
Lin, Yue-Jian [1 ]
Jin, Guo-Xin [1 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
来源：
ORGANOMETALLICS | 2011年 / 30卷 / 14期
关键词：
METAL-METAL BONDS; OXIDATIVE ADDITION; COMPLEXES;
D O I：
10.1021/om200399b
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
An N-heterocycle (pyrazine) utilized as a precursor was employed to construct multinuclear metallamacrocycle 1 though C-H activation and metal-metal bond formation under mild conditions. This iridamacrocycle was fully characterized by H-1 NMR, IR, and elemental analysis. In order to further confirm its structure, X-ray analysis was carried out, proving the hexanuclear iridium macrocyclic backbone of the complex.
引用
收藏
页码：3905 / 3907
页数：3
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