Properties of films and fibers obtained from Lewis acid-base complexed nylon 6,6

A nylon 6,6 complex with GaCl3 in nitromethane (4-5 wt% nylon 6,6) was prepared at 50-70 degrees C over 24 h for the purpose of disrupting the interchain hydrogen bonding between nylon 6,6 chains, resulting in amorphous nylon 6,6, and increasing the draw ratio for improving the performance of nylon 6,6 fibers. After drawing, complexed films and fibers were soaked in water to remove GaCl3 and regenerate pure nylon 6,6 films and fibers. FTIR, SEM, DSC, TGA, and mechanical properties were used for characterization of the regenerated nylon 6,6 films and fibers. The amorphous complexed nylon 6,6 can be stretched to high draw ratios at low strain rates, due to the absence of hydrogen bonding and crystallinity in these complexed samples. Draw ratios of 7-13 can be achieved for complexed fibers, under low strain rate stretching. This study indicates that nylon 6,6 fibers made from the GaCl3 complexed state, using a high molecular weight polymer, can reach initial moduli up to 13 GPa, compared to initial moduli of 6 GPa for commercial nylon 6,6 fibers. Lewis acid-base complexation of polyamides provides a way to temporarily suppress hydrogen bonding, potentially increasing orientation while drawing, and following regeneration of hydrogen bonding in the drawn state, to impart higher performance to their fibers. (c) 2008 Elsevier Ltd. All rights reserved.