CpxM(iii)-catalyzed enantioselective C-H functionalization through migratory insertion of metal-carbenes/nitrenes

被引：28

作者：

Pan, Chongqing ^{[1
]}

Yin, Si-Yong ^{[1
]}

Gu, Qing ^{[1
]}

You, Shu-Li ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 Lingling Lu, Shanghai 200032, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2021年 / 19卷 / 34期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

PLANAR CHIRAL FERROCENES; BOND FUNCTIONALIZATION; ASYMMETRIC CATALYSIS; LIGANDS; RH(III); ACTIVATION; RH; AMIDATIONS; COMPLEXES;

D O I：

10.1039/d1ob01248g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(CpM)-M-x(iii)-catalyzed enantioselective C-H functionalization reactions have progressed rapidly using either chiral cyclopentadienyl ligands or appropriate chiral carboxylic acids. In this context, highly reactive carbene and nitrene precursors can serve as effective C-H coupling partners, providing a straightforward and efficient approach to access chiral molecules. In this review, we highlight the developments in (CpM)-M-x(iii)-catalyzed enantioselective C-H functionalization reactions through migratory insertion of metal-carbenes/nitrenes by employing chiral (CpM)-M-x(iii) complexes or achiral (CpM)-M-x(iii) complexes combined with chiral carboxylic acids.

引用

页码：7264 / 7275

页数：12

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