NO oxidative activity of mesoporous LaMnO3 and LaCoO3 perovskite nanoparticles by facile molten-salt synthesis

被引:27
|
作者
Wang, Qianqian [1 ]
Ma, Liping [1 ]
机构
[1] Kunming Univ Sci & Technol, Fac Environm Sci & Engn, Kunming 650500, Yunnan, Peoples R China
基金
中国国家自然科学基金;
关键词
SELECTIVE CATALYTIC-REDUCTION; NH3-SCR REACTION; CO; MN; IDENTIFICATION; PERFORMANCE; STORAGE; DRIFTS; OXIDES; MODEL;
D O I
10.1039/c8nj04590a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
LaMnO3 and LaCoO3 perovskite nanoparticles have sprung up as the platinum group-metal (PGM)-free catalysts of NO oxidation to reduce NOX in the exhaust. In this paper, we present mesoporous LaMnO3 and LaCoO3 with rhombohedral structures prepared by a facile molten-salt synthesis method. LaMnO3 and LaCoO3 achieved NO oxidation performance with the highest NO conversions of 85% and 94% at 300 degrees C, which may be improved by K and Na introduced via flux.
引用
收藏
页码:2974 / 2980
页数:7
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