Enclathration of hydrogen by organic-compound clathrate hydrates

The properties of hydrogen enclathration by cyclic ethers and acetone clathrate hydrates were investigated by powder X-ray diffraction, Raman spectroscopic analysis and volumetric analysis. Powder X-ray diffraction profiles indicate that the hydrates are structure-II hydrates. The variation in lattice constant by hydrogen occupation was investigated. This result indicates that inclusion of H(2) atom within empty small cage changes size of host cages depending on type of guest molecule. Raman results show that the samples formed binary clathrate hydrate of hydrogen and each organic compound. The amount of encaged H(2) was found to be comparable to that of H(2)-THF binary hydrate. The trend of the changes for lattice constants is not related to the amount of encaged H(2). These results suggest that the organic compounds investigated in this study can be used as alternatives to THF for H(2) enclathration. (C) 2011 Elsevier Ltd. All rights reserved.