Field measurement evidence for an atmospheric chemical source of formic and acetic acids in the tropic.

被引：21

作者：

Sanhueza, E

Santana, M

Trapp, D

deServes, C

Figueroa, L

Romero, R

Rondon, A

Donoso, L

机构：

[1] UNIV STOCKHOLM,MISU,S-10691 STOCKHOLM,SWEDEN

[2] UNIV STOCKHOLM,ITM,S-10691 STOCKHOLM,SWEDEN

来源：

GEOPHYSICAL RESEARCH LETTERS | 1996年 / 23卷 / 09期

关键词：

D O I：

10.1029/96GL01038

中图分类号：

P [天文学、地球科学];

学科分类号：

07 ;

摘要：

The simultaneous measurements of atmospheric HCOOH, CH3COOH, H2O2, organic peroxides, HCHO, CH3CHO and isoprene made in the Venezuelan savannah region, in the wet season (September, 1993) and during the period of high solar irradiation is reported. The average concentrations (in ppbv) between 10:00 and 16:00 were: HCOOH 0.75 +/- 0.32, CH3COOH 0.56 +/- 0.28, H2O2 1.37 +/- 0.48, the total peroxides 1.83 +/- 0.60, HCHO 1.38 +/- 0.43, CH3CHO 0.35 +/- 0.15, and isoprene 2.18 +/- 0.78. A good correlation was observed between the concentrations (15 min averages) of both acids. The acids also correlate with isoprene (the most abundant olefin in the savannah atmosphere), H2O2 and the total peroxides. HCOOH also correlates well with HCHO and CH3CHO. These results support the hypothesis that significant amount of formic and acetic acids are produced in the tropical atmosphere as a result of the oxidation of reactive hydrocarbons.

引用

页码：1045 / 1048

页数：4

共 34 条

[1] MEASUREMENT OF ATMOSPHERIC FORMIC AND ACETIC-ACIDS - METHODS EVALUATION AND RESULTS FROM FIELD STUDIES
LAWRENCE, JE
KOUTRAKIS, P
[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1994, 28 (05) : 957 - 964
[2] Atmospheric formic and acetic acids in Venezuela
Sanhueza, E
Figueroa, L
Santana, M
[J]. ATMOSPHERIC ENVIRONMENT, 1996, 30 (10-11) : 1861 - 1873
[3] Atmospheric formic and acetic acids: An overview
Khare, P
Kumar, N
Kumari, KM
Srivastava, SS
[J]. REVIEWS OF GEOPHYSICS, 1999, 37 (02) : 227 - 248
[4] Bacteria in clouds biodegrade atmospheric formic and acetic acids
Nunez Lopez, Leslie
Amato, Pierre
Ervens, Barbara
[J]. ATMOSPHERIC CHEMISTRY AND PHYSICS, 2024, 24 (09) : 5181 - 5198
[5] Importance of secondary sources in the atmospheric budgets of formic and acetic acids
Paulot, F.
Wunch, D.
Crounse, J. D.
Toon, G. C.
Millet, D. B.
DeCarlo, P. F.
Vigouroux, C.
Deutscher, N. M.
Abad, G. Gonzalez
Notholt, J.
Warneke, T.
Hannigan, J. W.
Warneke, C.
de Gouw, J. A.
Dunlea, E. J.
De Maziere, M.
Griffith, D. W. T.
Bernath, P.
Jimenez, J. L.
Wennberg, P. O.
[J]. ATMOSPHERIC CHEMISTRY AND PHYSICS, 2011, 11 (05) : 1989 - 2013
[6] PHYSICAL AND CHEMICAL ADSORPTION OF FORMIC AND ACETIC ACIDS BY SPHERON 6
KIPLING, JJ
WRIGHT, EHM
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1963, 67 (09): : 1789 - &
[7] FORMIC AND ACETIC-ACIDS IN ATMOSPHERIC CONDENSATE IN WILMINGTON, NORTH-CAROLINA
WILLEY, JD
WILSON, CA
[J]. JOURNAL OF ATMOSPHERIC CHEMISTRY, 1993, 16 (02) : 123 - 133
[8] Emerging investigator series: aqueous oxidation of isoprene-derived organic aerosol species as a source of atmospheric formic and acetic acids
Bates, Kelvin H.
Jacob, Daniel J.
Cope, James D.
Chen, Xin
Millet, Dylan B.
Nguyen, Tran B.
[J]. ENVIRONMENTAL SCIENCE-ATMOSPHERES, 2023, 3 (11): : 1651 - 1664
[9] Relative contribution of biogenic and anthropogenic sources to formic and acetic acids in the atmospheric boundary layer
Glasius, M
Boel, C
Bruun, N
Easa, LM
Hornung, P
Klausen, HS
Klitgaard, KC
Lindeskov, C
Moller, CK
Nissen, H
Petersen, APF
Kleefeld, S
Boaretto, E
Hansen, TS
Heinemeier, J
Lohse, C
[J]. JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 2001, 106 (D7): : 7415 - 7426
[10] ATMOSPHERIC GEOCHEMISTRY OF FORMIC AND ACETIC-ACIDS AT A MID-LATITUDE TEMPERATE SITE
TALBOT, RW
BEECHER, KM
HARRISS, RC
COFER, WR
[J]. JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1988, 93 (D2): : 1638 - 1652

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