Bromobismuthates: Cation-induced structural diversity and Hirshfeld surface analysis of cation-anion contacts

被引：58

作者：

Adonin, Sergey A. ^{[1
,2
]}

Gorokh, Igor D. ^{[2
]}

Novikov, Alexander S. ^{[3
]}

Samsonenko, Denis G. ^{[1
,2
]}

Korolkov, Ilya V. ^{[1
,2
]}

Sokolov, Maxim N. ^{[1
,2
,4
]}

Fedin, Vladimir P. ^{[1
,2
]}

机构：

[1] SB RAS, Nikolaev Inst Inorgan Chem, Lavrentieva St 3, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, Pirogova St 2, Novosibirsk 630090, Russia

[3] St Petersburg State Univ, Inst Chem, Univ Skaya Nab 7-9, St Petersburg 199034, Russia

[4] Kazan Fed Univ, Alexander Butlerov Inst Chem, Lobachevskogo Str 1-29, Kazan 420008, Russia

来源：

POLYHEDRON | 2018年 / 139卷

基金：

俄罗斯科学基金会; 俄罗斯基础研究基金会;

关键词：

Halometalate; Halide complexes; Bismuth; Crystal structure; Hirshfeld surface analysis; PEROVSKITE SOLAR-CELLS; BIDENTATE BASE SYSTEMS; CRYSTAL-STRUCTURES; PHOTOCATALYTIC PROPERTIES; OPTICAL-PROPERTIES; SPECTROSCOPIC PROPERTIES; QUANTITATIVE-ANALYSIS; VIBRATIONAL-SPECTRA; HALIDE-COMPLEXES; HYBRID COMPOUND;

D O I：

10.1016/j.poly.2017.11.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of [BiBr6](3-) and bromide salts of various substituted pyridinium cations in excess of HBr result in a series of bromobismuthate anionic complexes of various geometry and nuclearity: [{BiBr4}(n)](n-), [Bi2Br9](3-) and [Bi2Br10](4-). Hirshfeld surface analysis for 19 crystal structure was performed; impact of various X-Br contacts on the crystal structures is discussed. (C) 2017 Elsevier Ltd. All rights reserved.

引用

页码：282 / 288

页数：7

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