Circular dichroism of optically active planar chiral cyclopalladium ferrocene derivatives. Investigation of the dimer-monomer equilibrium

被引：4
|
作者：
Sokolov, V. I. [1 ]
Bulygina, L. A. [1 ]
Babievskii, K. K. [1 ]
Yamskov, I. A. [1 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2007年 / 56卷 / 07期
基金：
俄罗斯基础研究基金会;
关键词：
chelate palladocycle; ferrocenes; optical activity; circular dichroism; Cotton effects; concentration dependence; dimer-monomer equilibrium;
D O I：
10.1007/s11172-007-0223-9
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The concentration dependence of the circular dichroism spectra of optically active dinuclear 2-dimethylaminomethylferrocenylpalladium chloride was studied in two solvents. The observed changes in the position and intensity of the Cotton effects were interpreted as a consequence of the dimer-monomer equilibrium.
引用
收藏
页码：1464 / 1466
页数：3
相关论文
共 6 条
  • [1] Circular dichroism of optically active planar chiral cyclopalladium ferrocene derivatives. Investigation of the dimer-monomer equilibrium
    V. I. Sokolov
    L. A. Bulygina
    K. K. Babievskii
    I. A. Yamskov
    Russian Chemical Bulletin, 2007, 56 : 1464 - 1466
  • [2] Synthesis and circular dichroism of the optically active dendrimers with the planar chiral ferrocene core
    V. I. Sokolov
    N. S. Khrushcheva
    K. K. Babievsky
    I. A. Yamskov
    Russian Chemical Bulletin, 2009, 58 : 1855 - 1857
  • [3] Synthesis and circular dichroism of the optically active dendrimers with the planar chiral ferrocene core
    Sokolov, V. I.
    Khrushcheva, N. S.
    Babievsky, K. K.
    Yamskov, I. A.
    RUSSIAN CHEMICAL BULLETIN, 2009, 58 (09) : 1855 - 1857
  • [4] STEREOCHEMISTRY OF METALLOCENES .26. ANALYSIS OF CIRCULAR DICHROISM OF FERROCENE-BAND OF OPTICALLY ACTIVE FERROCENE DERIVATIVES
    FALK, H
    HOFER, O
    MONATSHEFTE FUR CHEMIE, 1969, 100 (05): : 1507 - &
  • [5] Synthesis of optically-active planar chiral derivatives of ferrocene. Crystal structures of alkyne insertion products
    Zhao, G
    Wang, QG
    Mak, TCW
    TETRAHEDRON-ASYMMETRY, 1998, 9 (13) : 2253 - 2257
  • [6] Synthesis, circular dichroism, and third-order nonlinear optical properties of optically active porphyrin derivatives bearing four chiral citronellal moieties
    Lu, Jitao
    Wu, Lizhen
    Jing, Lu
    Xu, Xiaohong
    Zhang, Xiaomei
    DYES AND PIGMENTS, 2012, 94 (02) : 169 - 174
1