Palladium(II)-Catalyzed Enantioselective C-H Alkenylation of Ferrocenecarboxylic Acid

被引：25

作者：

Huang, Yanzhen ^{[1
]}

Pi, Chao ^{[1
]}

Cui, Xiuling ^{[1
]}

Wu, Yangjie ^{[1
]}

机构：

[1] Zhengzhou Univ, Key Lab Appl Chem Henan Univ, Coll Chem, Henan Key Lab Chem Biol & Organ Chem, Zhengzhou 450052, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2020年 / 362卷 / 06期

关键词：

Ferrocenecarboxylic acid; Free carboxylic acid-directed; Enantioselective; C-H alkenylation; PLANAR CHIRAL FERROCENES; ASYMMETRIC-SYNTHESIS; ACTIVATION; ARYLATION; REDOX; ALKYLATION; CHEMISTRY; ARYL; FUNCTIONALIZATION; DERIVATIVES;

D O I：

10.1002/adsc.201901195

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The palladium-catalyzed enantioselective C-H alkenylation of ferrocenecarboxylic acid has been developed. A series of 2-alkenyl ferrocenecarboxylic acids with planar chirality were obtained using molecular oxygen as an oxidant. This protocol starts from less expensive and readily available starting materials and provides the target products as a key intermediate in organic synthesis.

引用

页码：1385 / 1390

页数：6

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