Kesterite Inorganic-Organic Heterojunction for Solution Processable Solar Cells

被引：6
|
作者：
Data, P. [1 ,2 ,3 ]
Bialoglowski, M. [4 ]
Lyzwa, K. [4 ]
Bacewicz, R. [5 ]
Dluzewski, P. [6 ]
Lapkowski, M. [2 ,3 ]
Gregorkiewicz, T. [7 ]
Podsiadlo, S. [4 ]
Monkman, A. P. [1 ]
机构：
[1] Univ Durham, Dept Phys, South Rd, Durham DH1 3LE, England
[2] Silesian Tech Univ, Fac Chem, M Strzody 9, PL-44100 Gliwice, Poland
[3] Polish Acad Sci, Ctr Polymer & Carbon Mat, M Curie Sklodowskiej 34, PL-41819 Zabrze, Poland
[4] Warsaw Univ Technol, Fac Chem, Noakowskiego 3, PL-00664 Warsaw, Poland
[5] Warsaw Univ Technol, Fac Phys, Koszykowa 75, PL-00668 Warsaw, Poland
[6] Polish Acad Sci, Inst Phys, Al Lotnikow 32-46, PL-02668 Warsaw, Poland
[7] Univ Amsterdam, Van der Waals Zeeman Inst, Sci Pk 904, NL-1098 XH Amsterdam, Netherlands
来源：
ELECTROCHIMICA ACTA | 2016年 / 201卷
关键词：
solar cells; kesterite; P3HT; phenoxazine; electrochemistry; PHASE-SELECTIVE SYNTHESIS; CU2ZNSNS4; NANOCRYSTALS; LOW-COST; QUANTUM CONFINEMENT; OPTICAL-PROPERTIES; EFFICIENCY; ZN; MECHANISM; ELECTRODE; SIZE;
D O I：
10.1016/j.electacta.2016.03.132
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
New synthesis of solution processable kesterite and kesterite-phenoxazine nanopowders were presented. The direct band-gap semiconductor Cu2ZnSnS4 has attracted the attention of many due to its large absorption coefficient (alpha > 10(4) cm(-1)) and (optical) band-gap energy close to the optimal value for solar light conversion (1.4-1.6 eV). The presence of a kesterite nanocrystal structure has been investigated and confirmed by (HR) TEM, X-ray powder diffraction, EDX and EXAFS measurements. Low-temperature photoluminescence (PL) measurements indicate the absence of PL in the Cu2ZnSnS4 nanocrystals. Electrochemical studies helped to prove that an inorganic-organic heterojunction of nanokesterite-phenoxazine was obtained. Device studies showed a two fold improvement in efficiency upon addition of a kesterite or phenoxazines-kesterite layer. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：78 / 85
页数：8
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