On the mechanism of catalytic asymmetric dihydroxylation (AD) of alkenes

被引：0
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作者：
Lohray, BB
Bhushan, V
Nandanan, E
机构：
来源：
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY | 1996年 / 35卷 / 11期
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中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Evidence in support of the asymmetric dihydroxylation (AD) of alkenes to proceed possibly by a trigonal bipyramidal structure in which OsO4 is coordinated independently to the bridgehead nitrogen of bisalkaloid derivatives and not through a hexacoordinated mu-oxo-bridged bisosmium (VIII) is provided. Roth the quinuclidine moieties of the ligand are independently coordinated to one molecule of osmium tetroxide; however, in catalytic AD reaction only one of the osmium tetroxide reacts with the olefin.
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页码：1119 / 1122
页数：4
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