Reduction of N2 to ammonia and hydrazine utilizing H2 as the reductant

被引：89
|
作者：
Gilbertson, JD [1 ]
Szymczak, NK [1 ]
Tyler, DR [1 ]
机构：
[1] Univ Oregon, Dept Chem, Eugene, OR 97403 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 29期
关键词：
D O I：
10.1021/ja053030g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The trans-Fe(DMeOPrPE)2Cl2 complex (where DMeOPrPE = 1,2-bis(bis(methoxypropyl)phosphino)ethane) undergoes a series of reactions that involve the activation of both H2 and N2 to produce ammonia and hydrazine. A Leigh-type cycle was employed to achieve laboratory fixation of dinitrogen at room temperature and pressure utilizing H2 as the reductant. Copyright © 2005 American Chemical Society.
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收藏
页码：10184 / 10185
页数：2
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