Electrodeposition of Ni from Various Non-Aqueous Media: The Case of Alcoholic Solutions

被引:19
|
作者
Neurohr, K. [1 ]
Pogany, L. [1 ]
Toth, B. G. [1 ]
Revesz, A. [2 ]
Bakonyi, I. [1 ]
Peter, L. [1 ]
机构
[1] Hungarian Acad Sci, Wigner Res Ctr Phys, H-1121 Budapest, Hungary
[2] Eotvos Lorand Univ, Dept Mat Phys, H-1117 Budapest, Hungary
基金
匈牙利科学研究基金会;
关键词
NI(CF3COO)2-HALIDE-MEOH BATH; NICKEL ELECTRODEPOSITS; PHYSICAL-PROPERTIES; HYDROGEN-PRODUCTION; FILMS; ETHANOL; COPPER;
D O I
10.1149/2.0381507jes
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Although electrodeposition from aqueous media has been widely Used to obtain metallic deposits, there are cases where the application of non-aqueous solutions offers advantages over the traditional baths or even represents the only way to electrodeposit some metals. For this reason, a study of the electrodeposition of Ni from various alcoholic solutions was performed. Apart from a detailed cyclic voltammetry study of these solutions, the surface morphology, crystal structure and texture as well magnetic properties of the deposits have also been investigated. The best results were obtained with methanol as solvent, so results on Ni deposits prepared from this solution will be presented in more detail whereas the case of the other alcoholic solutions investigated will be summarized only briefly. Structural and magnetic properties of the deposits obtained have been compared to literature data on Ni samples obtained from various non-aqueous solvents. (C) The Author(s) 2015. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial No Derivatives 4.0 License (CC BY-NC-ND, http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits non-commercial reuse, distribution, and reproduction in any medium, provided the original work is not changed in any way and is properly cited. For permission for commercial reuse, please email: oa@electrochem.org. All rights-reserved.
引用
收藏
页码:D256 / D264
页数:9
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