Li ion conduction on plasticizer-added PVAc-based hybrid polymer electrolytes

被引：17

作者：

Ulaganathan, M. ^{[1
]}

Rajendran, S. ^{[1
]}

机构：

[1] Alagappa Univ, Sch Phys, Karaikkudi 630003, Tamil Nadu, India

来源：

IONICS | 2010年 / 16卷 / 07期

关键词：

Ionic conductivity; Plasticizer; Thermogravimetric analysis; Microstructure; Polymer electrolyte; COMPOSITE ELECTROLYTES; POLY(ETHYLENE OXIDE); LITHIUM BATTERIES; COMPLEXES;

D O I：

10.1007/s11581-010-0452-z

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Poly(vinyl acetate), poly(vinylidene fluoride-hexafluoropropylene), lithium perchlorate salt, and the different plasticizer-based gel polymer electrolytes were prepared by solvent-casting technique. The structural and the complex formation have been confirmed by X-ray diffraction spectroscopic analysis. Thermal stability of the different plasticizer-added electrolyte films has been analyzed by means of thermogravimetric analysis. Ionic conductivity of the electrolyte samples has been found as a function of temperature and the plasticizers. Among the various plasticizers, ethylene carbonate-based complexes exhibit maximum ionic conductivity value of the order of 10(-4) Scm(-1). Finally, the microstructure of the maximum ionic conductivity sample has been depicted with the help of scanning electron microscope analysis.

引用

页码：667 / 672

页数：6

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