3,4-Bis(bromomethyl)furazan and its N-oxide

被引:1
|
作者
Khakhalev, Artem V. [1 ]
Anisimov, Aleksei A. [2 ]
Sheremetev, Aleksei B. [1 ]
机构
[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, 47 Leninsky Ave, Moscow 119991, Russia
[2] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, 31 Leninsky Ave, Moscow 119991, Russia
关键词
dimethylglyoxime; furazan; furoxan; bromination; cyclization; DERIVATIVES; FURAZANS;
D O I
10.1007/s10593-022-03082-x
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The conditions for bromination of the methyl groups of dimethylglyoxime were found, and the resulting product, a 1,4-dioxane solvate of bis(bromomethyl)glyoxime, was used as a precursor for heterocyclizations involving cyclodehydration or oxidative cyclization of the oxime groups leading to the formation of furazan and furoxan rings, respectively.
引用
收藏
页码:263 / 266
页数:4
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