Study of the upper-critical dimension of the East model through the breakdown of the Stokes-Einstein relation

被引:2
|
作者
Kim, Soree [1 ]
Thorpe, Dayton G. [2 ]
Noh, Chanwoo [1 ]
Garrahan, Juan P. [3 ]
Chandler, David [2 ]
Jung, YounJoon [1 ]
机构
[1] Seoul Natl Univ, Dept Chem, Seoul 08826, South Korea
[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[3] Univ Nottingham, Sch Phys & Astron, Nottingham NG7 2RD, England
来源
JOURNAL OF CHEMICAL PHYSICS | 2017年 / 147卷 / 08期
基金
美国国家科学基金会;
关键词
SUPERCOOLED LIQUIDS; GLASS-TRANSITION; FIELD-THEORY; SPACE-TIME; DYNAMICS; FORMERS; SIMULATION; DIFFUSION; SCALE;
D O I
10.1063/1.4999791
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We investigate the dimensional dependence of dynamical fluctuations related to dynamic hetero-geneity in supercooled liquid systems using kinetically constrained models. The d-dimensional spin-facilitated East model with embedded probe particles is used as a representative super-Arrhenius glass forming system. We examine the existence of an upper critical dimension in this model by considering decoupling of transport rates through an effective fractional Stokes-Einstein relation, D similar to tau(-1+omega), with D and tau the diffusion constant of the probe particle and the relaxation time of the model liquid, respectively, and where omega > 0 encodes the breakdown of the standard Stokes-Einstein relation. To the extent that decoupling indicates non-mean-field behavior, our simulations suggest that the East model has an upper critical dimension at least above d = 10 and argue that it may actually be infinite. This result is due to the existence of hierarchical dynamics in the East model in any finite dimension. We discuss the relevance of these results for studies of decoupling in high dimensional atomistic models. Published by AIP Publishing.
引用
收藏
页数:7
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