XPS and Raman spectroscopic characterization of LiMn2O4 spinels

被引：220
|
作者：
Ramana, CV
Massot, M
Julien, CM
机构：
[1] Montana State Univ, Dept Phys, Surface Sci Ion Beam Lab, Bozeman, MT 59717 USA
[2] Univ Paris 06, LPMC, F-75252 Paris, France
[3] Univ Paris 06, LMDH, F-75015 Paris, France
来源：
SURFACE AND INTERFACE ANALYSIS | 2005年 / 37卷 / 04期
关键词：
manganese oxides; spinel; lithium batteries; XPS; Raman scattering; LITHIUM BATTERIES; MANGANESE OXIDES;
D O I：
10.1002/sia.2022
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Surface analysis of lithium manganese oxides synthesized by the melt-impregnation method has been made by x-ray photoelectron spectroscopy. These results revealed the change in the average oxidation state of Mn cations upon lithium substitution in Li1+deltaMn2-deltaO4 spinels. Studies of the local structure characterized by Raman scattering show the Mn-O bonding evolution as a function of the replacement of manganese cations. Modification in the trigonal distortion of MnO6 octahedra is evidenced by insertion of lithium ions into the octahedral holes of the [B-2]O-4 spinel framework. Copyright (c) 2005 John Wiley S Sons, Ltd.
引用
收藏
页码：412 / 416
页数：5
相关论文
共 50 条
  • [1] Hydride lithiation of spinels LiMn2O4
    Buzanov, G. A.
    Nipan, G. D.
    Zhizhin, K. Yu.
    Kuznetsov, N. T.
    DOKLADY CHEMISTRY, 2016, 471 : 330 - 333
  • [2] Hydride lithiation of spinels LiMn2O4
    G. A. Buzanov
    G. D. Nipan
    K. Yu. Zhizhin
    N. T. Kuznetsov
    Doklady Chemistry, 2016, 471 : 330 - 333
  • [3] Cation ordering in substituted LiMn2O4 spinels
    Strobel, P
    Ibarra-Palos, A
    Poinsignon, C
    SOLID STATE IONICS-2002, 2003, 756 : 225 - 230
  • [4] Lithium Manganese Oxide (LiMn2O4)by XPS
    Militello, Maria C.
    Gaarenstroom, Stephen W.
    Surface Science Spectra, 2001, 8 (03): : 207 - 213
  • [5] Mechanism of the electrochemical insertion of lithium into LiMn2O4 spinels
    Univ of Pennsylvania, Philadelphia, United States
    J Electrochem Soc, 2 (459-465):
  • [6] Mechanism of the electrochemical insertion of lithium into LiMn2O4 spinels
    Liu, W
    Kowal, K
    Farrington, GC
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (02) : 459 - 465
  • [7] A Raman study of spinel LiMn2O4
    Wang, CZ
    Gong, J
    Liu, W
    Wei, YJ
    Wu, F
    Chen, G
    CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2003, 19 (03) : 344 - 346
  • [8] A Raman Study of Spinel LiMn2O4
    WANG Chun-zhong 1
    2. Institute of Condensed Matter Physics
    3. Beijing Institute of Technology
    Chemical Research in Chinese Universities, 2003, (03) : 344 - 346
  • [9] Electrochemical characterization of LiMn2O4
    Dept. of Electromechanical Engineering, Heilongjiang Institute of Technology, Harbin 150050, China
    不详
    Cailiao Kexue yu Gongyi, 2008, 2 (232-234+238):
  • [10] Structural and electrochemical study of cobalt doped LiMn2O4 spinels
    Liu, RS
    Shen, CH
    SOLID STATE IONICS, 2003, 157 (1-4) : 95 - 100
12345