Hexamethylenetetramine-bromine: A novel reagent for selective regeneration of carbonyl compounds from oximes and tosylhydrazones

被引：22
|
作者：
Bandgar, BP
Admane, SB
Jare, SS
机构：
[1] Swami Ramanand Teerth Marathwada Univ, Sch Chem Sci, Organ Chem Res Lab, Nanded 431602, Maharashtra, India
[2] RBNB Coll, Dept Chem, Shrirampur 413709, India
来源：
JOURNAL OF CHEMICAL RESEARCH-S | 1998年 / 03期
关键词：
D O I：
10.1039/a706884k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Hexamethylenetetramine-bromine (HMTAB) has been found to be an efficient and selective reagent for the mild oxidative cleavage of the C=N of oximes and tosylhydrazones to yield their corresponding carbonyl compounds in good to excellent yields under mild conditions.
引用
收藏
页码：154 / 155
页数：3
相关论文
共 50 条
  • [1] Facile regeneration of carbonyl compounds from oximes and tosylhydrazones with TBHP
    Barhate, NB
    Gajare, AS
    Wakharkar, RD
    Sudalai, A
    TETRAHEDRON LETTERS, 1997, 38 (04) : 653 - 656
  • [2] Hexamethylenetetramine-bromine on wet alumina: Rapid oxidation of alcohols to carbonyl compounds in solventless system using microwaves
    Heravi, MM
    Ajami, D
    Noushabadi, AM
    IRANIAN JOURNAL OF CHEMISTRY & CHEMICAL ENGINEERING-INTERNATIONAL ENGLISH EDITION, 1999, 18 (02): : 88 - 90
  • [3] A new application of N-bromosaccharin as a selective and efficient oxidative reagent for regeneration of carbonyl compounds from oximes
    Khazaei, A
    Manesh, AA
    Rostami, A
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2004, 179 (12) : 2483 - 2486
  • [4] Tetrameric DABCO-bromine complex: A novel reagent for regeneration of carbonyl compounds from aldoximes and ketoximes
    Heravi, MM
    Derikvand, F
    Ghassemzadeh, M
    SYNTHETIC COMMUNICATIONS, 2006, 36 (05) : 581 - 585
  • [5] Dichlorophenobarbital: An Efficient and Selective Reagent for Deoximation of Oximes to the Carbonyl Compounds
    Shiri, Azam
    Khoramabadi-Zad, Ahmad
    Esmaili-Nezhad, Fateme
    LETTERS IN ORGANIC CHEMISTRY, 2018, 15 (10) : 833 - 837
  • [6] Regeneration of carbonyl compounds from the corresponding oximes
    Corsaro, A.
    Chiacchio, U.
    Pistarà, V.
    Synthesis, 2001, (13) : 1903 - 1931
  • [7] Photosensitized regeneration of carbonyl compounds from oximes
    de Lijser, HJP
    Fardoun, FH
    Sawyer, JR
    Quant, M
    ORGANIC LETTERS, 2002, 4 (14) : 2325 - 2328
  • [8] Regeneration of carbonyl compounds from the corresponding oximes
    Corsaro, A
    Chiacchio, U
    Pistará, V
    SYNTHESIS-STUTTGART, 2001, (13): : 1903 - 1931
  • [9] Highly selective regeneration of carbonyl compounds from their oximes and semicarbazones in aqueous medium
    Bhar, S
    Guha, S
    SYNTHETIC COMMUNICATIONS, 2005, 35 (09) : 1183 - 1188
  • [10] Regeneration of carbonyl compounds from oximes, semicarbazones and tosylhydrazones with calcium hypochlorite and moist montmorillonite K-10
    Movassagh, Barahman
    Dahaghin, Ebrahim
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2006, 45 (06): : 1541 - 1543
12345