Poly[[tetraaquabis[μ3-1-ethyl-6-fluoro-4-oxo-7-(piperazinium-1-yl)-1H-quinoline-3-carboxylato]dinickel(II)] hydroxidenitrate]

被引:1
|
作者
Song, Wen-Dong [2 ]
Wan, Yi-Ling [3 ]
Hong, Peng-Zhi [3 ]
Ng, Seik Weng [1 ]
机构
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[2] Guangdong Ocean Univ, Coll Sci, Zhanjiang 524088, Peoples R China
[3] Guangdong Ocean Univ, Sch Food Sci & Technol, Zhanjiang 524088, Peoples R China
关键词
D O I
10.1107/S1600536807062885
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Ni-2(C16H18FN3O3)(2)(H2O)(4)](OH)(NO3), the cationic [Ni-2(C16H18FN3O3)(2)(H2O)(4)](2+) building units are linked through Ni-O-carboxylate and Ni-N-amino bridges into a layer structure. The two independent nickel atoms lie on inversion centres: one adopts an NiO6 octahedral geometry, the other a trans-NiN2O4 octahedral arrangement. The charge-balancing hydroxide and nitrate ions are of half site occupancy each. A network of O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds helps to establish the packing.
引用
收藏
页码:M70 / U689
页数:11
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