(1R*,5S*,6S*,7R*)-6,7-dihydroxy-6-hydroxymethyl-2-oxabicyclo[3.2.0]heptan-3-one

被引:3
|
作者
Caddy, J [1 ]
Williams, DBG [1 ]
Roodt, A [1 ]
Muller, A [1 ]
机构
[1] Rand Afrikaans Univ, Dept Chem & Biochem, ZA-2006 Johannesburg, South Africa
关键词
D O I
10.1107/S1600536803014557
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The crystal structure analysis of the title compound, C7H10O5, shows that a four-five lactonization instead of a four - six self condensation took place during the reaction sequence. The structure is stabilized by strong hydrogen-bonding interactions that serve to form a layer structure. The absolute configuration was assigned based on the chemical synthesis from a starting material of known chirality.
引用
收藏
页码:O1095 / O1097
页数:3
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