The synthesis of N-benzoyl aziridines from β-benzamidoalkyl phenyl selenides

被引：0
|
作者：
Ward, VR [1 ]
Cooper, MA [1 ]
Ward, AD [1 ]
机构：
[1] Univ Adelaide, Dept Chem, Adelaide, SA 5005, Australia
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2001年 / 171卷
关键词：
selenides; selenones; oxazolines; aziridines;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
beta -Benzamidoalkyl phenyl selenides can be oxidised, using mCPBA, to the corresponding selenones which can be cyclised to oxazolines or aziridines depending on the reaction conditions. In neutral or weakly basic conditions the oxazoline is the major product but if the oxidation is conducted at -60 degreesC then the corresponding aziridine is formed in high yields using strongly basic conditions. The synthesis of a range of bicyclic N-benzoyl aziridines is described.
引用
收藏
页码：449 / 455
页数：7
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