Superpositions of chiral states in the presence of electric dipole, magnetic dipole, and electric quadrupole interactions

被引:7
|
作者
Athalye, VS [1 ]
Kumar, A
机构
[1] Univ Bombay, Thakur Coll, Dept Phys, Bombay 400101, Maharashtra, India
[2] Tata Inst Fundamental Res, Homi Bhaba Ctr Sci Educ, Bombay 400088, Maharashtra, India
来源
JOURNAL OF CHEMICAL PHYSICS | 2005年 / 122卷 / 17期
关键词
Degrees of freedom (mechanics) - Hamiltonians - Matrix algebra - Molecular dynamics - Perturbation techniques - Polarization - Radiation - Vacuum applications;
D O I
10.1063/1.1883645
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This paper is a straightforward generalization of Maierle-Harris proposal regarding parity implications on the superpositions of chiral states of a molecule. It is shown that the inclusion of electric quadrupole and magnetic dipole interactions removes several of restrictions on the preparation of superpositions of L and R states of a chiral molecule. It is also found that the dephasing of L and R superpositions, due to the spontaneous emission from the chiral molecule, has opposing contributions from electric quadrupole-magnetic dipole and electric dipole interactions. 2005 American Institute of Physics.
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页数:3
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