Bis(μ-quinoline-2-carboxylato)-κ3 N,O:O;κ3 O:N,O-bis[(acetato-κ2 O,O')(methanol-κO)lead(II)]

被引:5
|
作者
Mohammadnezhad, Gholamhossein [2 ]
Ghanbarpour, Ali Reza [2 ]
Amini, Mostafa M. [2 ]
Ng, Seik Weng [1 ]
机构
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[2] Shahid Beheshti Univ, Dept Chem, Tehran 1983963113, Iran
关键词
D O I
10.1107/S1600536810027777
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The dinuclear title compound, [Pb-2(C10H6NO2)(2)(CH3COO)(2)(CH3OH)(2)], lies across an inversion center. The methanol-coordinated PbII atom is chelated by the acetate anion as well as by the quinoline-2-carboxylate anion. One O atom of the quinoline-2-carboxylate anion bridges two symmetry-related PbII atoms, forming the dinuclear compound. Aside from the six atoms connected to the PbII atom by regular coordination bonds, the structure features a long Pb...O interaction [3.145 (3) A] that gives rise to a distorted Psi-square-antiprismatic geometry at the metal center. The H atom of the methanol is hydrogen bonded to an O atom of the acetate.
引用
收藏
页码:M963 / U938
页数:10
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