Low-temperature interaction between hydrogen bromide and ozone

被引：0

作者：

Savilov, SV ^{[1
]}

Yagodovskaya, TV ^{[1
]}

Zosimov, AV ^{[1
]}

Lunin, VV ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119899, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY | 2003年 / 77卷 / 06期

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The heterogeneous chemical reactions between ozone and HBr and a solution of between ozone and HBr adsorbed on the surface of ice were studied in the temperature range 77-223 K. The reagents interacted instantaneously with the formation of dark brown, golden yellow, and yellow-orange condensates. According to the low-temperature IR spectra, the reaction products were Br2O, Br2O3, BrO2, and Br2O4 bromine oxides. The initial product was Br2O, which afterward underwent successive oxidation. Ab initio quantum-chemical calculations were performed to determine the structures and relative stabilities of the specified bromine oxides.

引用

页码：930 / 934

页数：5

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