Phason defects in Al-Pd-Mn approximant phases

被引:64
|
作者
Klein, H [1 ]
Audier, M [1 ]
Boudard, M [1 ]
deBoissieu, M [1 ]
Beraha, L [1 ]
Duneau, M [1 ]
机构
[1] ECOLE POLYTECH,CTR PHYS THEOR,F-91128 PALAISEAU,FRANCE
关键词
D O I
10.1080/01418619608244385
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Structural defects, observed by TEM, in Al-Pd-Mn approximant phases are identified as phason defects. Assuming their motion under an applied shear strain, it is shown that two approximant phases can be related between them by a phase transformation occurring through plastic deformations. Then, other approximant phases, experimentally observed, can be interpreted as intermediate states of such a phase transformation. Atomic motions corresponding to these phason shifts are partly examined on the basis of HREM observations and crystallographic data, obtained from a single-crystal X-ray study on one of these approximants. The description of this transformation in six-dimensional hyperspace is proposed in order to establish a relationship with the icosahedral quasicrystalline state. The possibility that a plastic deformation of the icosahedral phase, occurring without the strain-hardening effect, could only result in a motion of phason defects is briefly discussed.
引用
收藏
页码:309 / 331
页数:23
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