Anhydrous lead(II) heptanoate

被引：42
|
作者：
Lacouture, F
François, M
Didierjean, C
Rivera, JP
Rocca, E
Steinmetz, J
机构：
[1] Univ Nancy 1, Lab Chim Solide Mineral, UMR 7555, Fac Sci, F-54506 Vandoeuvre Nancy, France
[2] Univ Nancy 1, Lab Cristallog & Modelisat Mat Mineraux & Biol, UPRESA 7036, Fac Sci, F-54506 Vandoeuvre Nancy, France
[3] Univ Geneva, Dept Chim Minerale Analyt & Appl, CH-1211 Geneva, Switzerland
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2001年 / 57卷
关键词：
D O I：
10.1107/S0108270101001615
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, catena-poly[[(heptanoato-O,O')lead(II)]-mu -heptanoato-O,O' :O:O'], [Pb(C7H13O2)(2)], is a metallic soap which can be used as a corrosion inhibitor since it forms a passive film at the Pb surface. Its structure is characterized by two-dimensional layers parallel to the bc plane. The layers are packed through van der Waals interactions along the a direction and form blocks parallel to (001). The 6s(2) lone pair of electrons on Pb-II is stereochemically active in this compound, which leads to a hemidirected octahedral geometry for the O-environment around the Pb atoms.
引用
收藏
页码：530 / 531
页数：2
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