Bidentate ligands formed by self-assembly

被引：102
|
作者：
Slagt, VF [1 ]
van Leeuwen, PWNM [1 ]
Reek, JNH [1 ]
机构：
[1] Univ Amsterdam, Inst Mol Chem, Amsterdam, Netherlands
来源：
CHEMICAL COMMUNICATIONS | 2003年 / 19期
关键词：
D O I：
10.1039/b306683e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel supramolecular strategy to prepare bidentate ligands via the assembly of functionalised monomeric ligands on a dimeric zinc(II) porphyrin template is presented; the assembled bidentate ligands show chelating behaviour and their rhodium complexes display enhanced selectivity in the hydroformylation compared to the non-template analogue.
引用
收藏
页码：2474 / 2475
页数：2
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