Study on the coordination polymer of electropolyurushiol and rare earth

被引：3

作者：

Tang, JY ^{[1
]}

Zhang, WG ^{[1
]}

Gao, F ^{[1
]}

机构：

[1] Fujian Teachers Univ, Inst Polymer Sci, Fuzhou 350007, Peoples R China

来源：

ACTA PHYSICO-CHIMICA SINICA | 2000年 / 16卷 / 12期

关键词：

urushiol; electrochemical polymerization; rare earths; coordination polymer;

D O I：

10.3866/PKU.WHXB20001206

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The coordination polymer of rare earth was prepared by the reaction of rare earth triisopropoxide (Pr, Nd, Eu) with electropolyurushiol polymerization(EPU). The structure and properties of the coordination polymer were characteized by FT-IR, Fluorescence, XPS, DMTA and AES. The results indicated that there is of coordination interaction between rare earth ion with electropolyurushiol in the coordination polymer, thus cross-link was formed. Therefore the coordination polymer was insoluble in most organic solvents, and glass transition temperature increase and heat resistance were enhanced considerably.

引用

页码：1086 / 1092

页数：7

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