The Use of Original Structure-Directing Agents for the Synthesis of EMC-1 Zeolite

被引：4

作者：

Daou, T. J. ^{[1
]}

Dhainaut, J. ^{[1
,2
]}

Chappaz, A. ^{[1
,3
]}

Bats, N. ^{[2
]}

Harbuzaru, B. ^{[2
]}

Chaumeil, H. ^{[3
]}

Defoin, A. ^{[3
]}

Rouleau, L. ^{[2
]}

Patarin, J. ^{[1
]}

机构：

[1] Univ Haute Alsace, CNRS, Equipe Mat Porosite Controlee MPC, Inst Sci Mat Mulhouse IS2M,UMR 7361,ENSCMu, F-68093 Mulhouse, France

[2] IFP Energies Nouvelles, Rond Point Echangeur Salaize, F-69360 Solaize, France

[3] Univ Haute Alsace, Lab Chim Organ & Bioorgan COB, EA 4566, ENSCMu, F-68093 Mulhouse, France

来源：

OIL & GAS SCIENCE AND TECHNOLOGY-REVUE D IFP ENERGIES NOUVELLES | 2015年 / 70卷 / 03期

关键词：

RATIONAL DESIGN; 18-CROWN-6; CATALYSTS; TEMPLATE; ETHERS; FAU;

D O I：

10.2516/ogst/2014030

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

By using a steric approach, it is possible to design templates matching closely with an inorganic framework. Herein, the design, synthesis and successful application of several di(azacrown ether) templates to direct the formation of EMC-1 zeolite (FAU-type) are reported. Following a high throughput experiment design, the synthesis gel composition was optimized to obtain well-crystallized materials. Taking into account their respective crystallization rates, their textural and morphological properties were comparable to their counterparts, typically structured by 15-crown-5 ether.

引用

页码：447 / 454

页数：8

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