Solvothermal synthesis of ZnS[C2H4(NH2)2]0.5 nanosheets

被引：13
|
作者：
Mosca, R. [1 ]
Ferro, P. [1 ]
Calestani, D. [1 ]
Nasi, L. [1 ]
Besagni, T. [1 ]
Licci, F. [1 ]
机构：
[1] IMEM CNR, I-43124 Fontanini Parma, Italy
来源：
CRYSTAL RESEARCH AND TECHNOLOGY | 2011年 / 46卷 / 08期
关键词：
ZnS(ethylenediamine); organic-inorganic hybrid; solvothermal synthesis; ZNS; ETHYLENEDIAMINE; DENDRITES; ROUTE;
D O I：
10.1002/crat.201000690
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
ZnS(en)(0.5) complex (en=ethylenediamine) can be synthesized by solvothermal route as thin sheet-like crystals using en as the single solvent. We studied the influence of the main synthesis parameters (i.e. temperature, pressure, time, reactant type and concentration) on the compound crystallization kinetics to achieve control on shape and dimensions of the ZnS(en)(0.5) nanoplatelets. We achieved a significant reduction of the platelet dimensions, while maintaining acceptable yield, by using a single piece of metal zinc as the Zn2+ source. (C) 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
引用
收藏
页码：818 / 822
页数：5
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