Computational study of the thermal rearrangement of acetoxy(methoxy) carbene

被引：5

作者：

Czardybon, W ^{[1
]}

Warkentin, J ^{[1
]}

Werstiuk, NH ^{[1
]}

机构：

[1] McMaster Univ, Dept Chem, Hamilton, ON L8S 4M1, Canada

来源：

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 2005年 / 18卷 / 06期

关键词：

acetoxy(methoxy)carbene; carbene; concerted; computation; rearrangement;

D O I：

10.1002/poc.899

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Thermolysis of 2-acetoxy-2-methoxy-5,5-dimethyl-Delta(3)- 1,3,4-oxadiazoline affords acetoxy(methoxy)carbene. Thermal rearrangement of acetoxy(methoxy)carbene to methyl pyruvate is a concerted 1,2-migration, avoiding a potential radical-pair mechanism. Copyright (c) 2005 John Wiley & Sons, Ltd.

引用

页码：486 / 490

页数：5

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