High-Temperature Reaction of Al2O3-Si in Reduction Atmosphere

被引:0
|
作者
Zhu Hongxi [1 ]
Deng Chengji [1 ]
Li Junying [1 ]
Bai Chen [1 ]
机构
[1] Wuhan Univ Sci & Technol, Hubei Prov Key Lab Refractories & Ceram, Minist Prov Jointly Constructed Cultivat Base, State Key Lab, Wuhan 430081, Peoples R China
关键词
Al2O3-Si materials; Sialon; reaction process;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Corundum and industrial Si buried in carbon were reacted between 1400 similar to 1600 degrees C, and SiC, O'-Sialon and SiO2 were formed at T < 1550 degrees C. The products were analyzed by XRD, and the dynamic mechanism in association to the formation of Sialon was discussed. X-Sialon formed at T > 1550 degrees C. The products of Si3N4, SiO2 and SiC were formed from the reaction between Si and N-2, or Si and CO. Si2N2O and O'-Sialon were detected for the products. The sintered temperature and the starting compositions of the raw materials has great effects on the reaction rate and phase compositions of the products.
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页码:130 / 133
页数:4
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