Intramolecular carbonylation reactions with recyclable palladium-complexed dendrimers on silica: Synthesis of oxygen, nitrogen, or sulfur-containing medium ring fused heterocycles

被引：148

作者：

Lu, SM ^{[1
]}

Alper, H ^{[1
]}

机构：

[1] Univ Ottawa, Ctr Catalysis Res & Innovat, Dept Chem, Ottawa, ON K1N 6N5, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 42期

关键词：

D O I：

10.1021/ja053650h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Palladium-complexed dendrimers supported on silica were evaluated as catalysts for intramolecular carbonylation reactions. The results showed that dendritic catalysts display high activity, affording oxygen, nitrogen, or sulfur-containing seven- or eight-membered ring fused heterocycles in excellent yields. Moreover, these catalysts have competitive advantages in that they can be easily recovered by simple filtration in air and reused for up to eight cycles with only a slight loss of activity.

引用

页码：14776 / 14784

页数：9

共 17 条

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