A simple method for determining the lattice parameter and chemical composition in ternary bcc-Fe rich nanocrystals

被引:4
|
作者
Moya, Javier A. [1 ]
Caramella, Soledad Gamarra [1 ]
Marta, Leonardo J. [1 ]
Berejnoi, Carlos [2 ]
机构
[1] Univ Catolica Salta, INTECIN UBA CONICET, Grp Interdisciplinario Mat, IESIING, Salta, Argentina
[2] Univ Nacl Salta, Fac Ingn, Salta, Argentina
关键词
Nanostructured materials; Metals and alloys; Crystal structure; Phase diagrams; X-ray diffraction; Mossbauer spectroscopy; MOSSBAUER-SPECTROSCOPY; MAGNETIC-PROPERTIES; HYPERFINE-FIELD; SI; IRON; BEHAVIOR; ALLOYS; MOMENT; BINARY;
D O I
10.1016/j.jallcom.2015.01.014
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Charts containing lattice parameters of Fe-1 (x)(M, N)(x) ternary systems with M and N = Si, Al, Ge or Co, and 0 <= x <= similar to 0.3, were developed by implementing a linear relationship between the respective binary alloys with the same solute content of the ternary one. Charts were validated with experimental data obtained from literature. For the Fe-Co-Si system, the linear relationship does not fit the experimental data. For the other systems (except the Fe-Co-Ge one where no experimental data was found), the lineal relationship constitute a very good approximation. Using these charts and the lattice parameter data obtained from X-ray diffraction technique combining with the solute content data obtained from Mossbauer spectroscopy technique it is possible to determine the chemical composition of nanograins in soft magnetic nanocomposite materials and some examples are provided. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:99 / 104
页数:6
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