Structures, spectroscopy and modeling of a rare set of isomeric copper(II) complexes

被引：6
|
作者：
Comba, Peter [1 ]
Pandian, Shanthi [1 ]
Wadepohl, Hubert [1 ]
Wiesner, Sebastian [1 ]
机构：
[1] Heidelberg Univ, Inst Anorgan Chem, D-69120 Heidelberg, Germany
来源：
INORGANICA CHIMICA ACTA | 2011年 / 374卷 / 01期
关键词：
Distortional isomerism; Density functional theory; Ligand field; Diastereo isomer; Copper bispidine; Axial and rhombic; TRANSITION-METAL-COMPLEXES; BOND-STRETCH ISOMERISM; MOLECULAR-MECHANICS; BISPIDINE; LIGANDS; STABILIZATION; TETRADENTATE; COMPOUND; SPECTRA; STATE;
D O I：
10.1016/j.ica.2011.02.047
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The structures and spectroscopic properties of various conformations of two diasteromeric pairs of enantiomers of pentacoordinate Cu-II bispidine complexes with chiral tetradentate ligands are reported. With one of the ligands an interesting type of distortional isomerism was observed experimentally, and this was studied in detail on the basis of the experimental structural and spectroscopic data (UV-Vis-NIR, EPR) and a DFT-, MM- and ligand-field-theory-based analysis. (C) 2011 Elsevier B. V. All rights reserved.
引用
收藏
页码：422 / 428
页数：7
相关论文
共 50 条
  • [1] Selenoether complexes of copper(II) - Synthesis, spectroscopy and structures
    Black, JR
    Levason, W
    JOURNAL OF COORDINATION CHEMISTRY, 1996, 37 (1-4) : 315 - 325
  • [2] Copper(II) complexes of three isomeric bis(tacn) ligands: Syntheses, structures and properties
    Coghlan, Campbell J.
    Campi, Eva M.
    Batten, Stuart R.
    Jackson, W. Roy
    Hearn, Milton T. W.
    POLYHEDRON, 2016, 105 : 246 - 252
  • [3] Theoretical modeling of the structures and properties of copper(II) and Nickel(II) complexes with Schiff bases
    Rogachev, AY
    Nemukhin, AV
    Granovskii, AA
    Kuz'mina, NP
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2005, 50 (07) : 1036 - 1043
  • [4] COPPER(II) COMPLEXES IMMOBILIZED ON A POLYMERIC MATRIX - THERMODYNAMICS, SPECTROSCOPY, AND MOLECULAR MODELING
    CHIESSI, E
    BRANCA, M
    PALLESCHI, A
    PISPISA, B
    INORGANIC CHEMISTRY, 1995, 34 (10) : 2600 - 2609
  • [5] STRUCTURES OF SALICYLALDIMINE COPPER(II) COMPLEXES
    CSASZAR, J
    ACTA PHYSICA ET CHEMICA, 1982, 28 (1-2): : 35 - 43
  • [6] New robust bleomycin analogues: Synthesis, spectroscopy, and crystal structures of the copper(II) complexes
    Kurosaki, H
    Hayashi, K
    Ishikawa, Y
    Goto, M
    Inada, K
    Taniguchi, I
    Shionoya, M
    Kimura, E
    INORGANIC CHEMISTRY, 1999, 38 (12) : 2824 - 2832
  • [7] Synthesis and spectral studies of copper(II) and nickel(II) complexes of isomeric and heterocyclic benzoylhydrazones
    Rao, S
    Reddy, KH
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1996, 35 (08): : 681 - 686
  • [8] Preparation and spectral properties of nickel(II) and copper(II) complexes with two isomeric cyclohexylcyclams
    Sakata, K
    Odamura, T
    Kanbara, Y
    Nibu, T
    Hashimoto, M
    Tsuge, A
    Moriguchi, Y
    POLYHEDRON, 1998, 17 (09) : 1463 - 1470
  • [9] SYNTHESIS AND STRUCTURES OF COPPER(II) THIOLATE COMPLEXES
    ANDERSON, OP
    PERKINS, CM
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1981, 182 (AUG): : 294 - INOR
  • [10] Influence of heterocycles arrangement in structural isomeric ligands on coordination sphere of copper(II) complexes:: Crystal structures and spectroscopic characterization
    Maldonado-Rogado, M. A.
    Vinuelas-Zahinos, E.
    Luna-Giles, F.
    Bernalte-Garcia, A.
    POLYHEDRON, 2007, 26 (06) : 1173 - 1181
12345