Study on properties and structural parameters of microemulsion CTAB/butanol/cyclohexane/salt aqueous solution

被引:0
|
作者
Chen, YJ
Qiu, GM [1 ]
Tian, YG
Fang, L
Xiao, LJ
Sun, YB
机构
[1] Changchun Univ Sci & Technol, Sch Mat & Chem Technol, Changchun 130022, Peoples R China
[2] Northeastern Univ, Sch Met & Mat, Shenyang 110006, Peoples R China
[3] Shenyang Inst Chem Technol, Sch Appl Chem, Shenyang 110142, Peoples R China
[4] Wenzhou Univ, Dept Chem, Wenzhou 325027, Peoples R China
[5] Jilin Univ, Coll Mat Sci & Engn, Changchun 130026, Peoples R China
关键词
inorganic chemistry; CTAB; microemulsion; phase diagrams; structural parameters; rare earths;
D O I
暂无
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The phase diagrams of microemulsion CTAB/butanol/cyclohexane/aqueous solution of nitrate (or aqueous solution of ammonium salt) were determined and the structural parameters and Delta G*(0 -> i) were obtained by means of dilution method and theoretical calculation. The effect of different w/s and salt concentration on the stability and structural parameters of microemulsion were investigated. The result shows that with the increase of w/s, the area of microemulsion and N-d decrease, R-w, l and a increase; with the increase of salt concentration, the area of microemulsion, l and Nd decrease, Delta G*(0 -> 1), R-w and n increase. Theoretical basis of preparing size-controlled long afterglow luminescence materials and study of the relationship between fluorescence properties and particle size are provided.
引用
收藏
页码:271 / 275
页数:5
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