In Situ U-Pb Geochronology of Calcite from the World's Largest Antimony Deposit at Xikuangshan, Southern China

The Xikuangshan antimony (Sb) deposit is the world's largest known Sb deposit. Due to the lack of suitable minerals for reliable high-precision radiometric dating, it remains difficult to determine the exact age of Sb mineralization in this deposit. Here, we report the first LA-MC-ICP-MS U-Pb ages of syn-stibnite calcite from this deposit. The dating results indicate the presence of at least two stages of Sb mineralization in the Xikuangshan ore district. The calcite-stibnite veins in the Daocaowan ore block probably formed during the Paleocene (58.1 +/- 0.9 Ma), representing an early stage of Sb mineralization, while the quartz-stibnite vein in the Feishuiyan ore block probably formed during the Eocene (50.4 +/- 4.4 Ma, 50.4 +/- 5.0 Ma, and 51.9 +/- 1.6 Ma), representing a late stage of Sb mineralization. The new calcite U-Pb ages are significantly younger than the calcite Sm-Nd ages (124.1 +/- 3.7 Ma, 155.5 +/- 1.1 Ma) reported by previous researchers. We suggest that Sb mineralization of the South China antimony metallogenic belt may be related to tectono-thermal events during Paleogene, possibly linked to high heat flow during the subduction (ca. 60-40 Ma) of the Pacific Plate beneath the Eurasian Plate and/or the Indo-Asian Collision (began at ca. 61 Ma). The young in situ U-Pb ages of calcite challenge the idea of late Mesozoic Sb mineralization in the South China antimony metallogenic belt, suggesting the requirement for more high-precision dating studies.