Cross-Dehydrogenative Coupling Reactions of sp3-Hybridized C-H Bonds

被引:255
|
作者
Yoo, Woo-Jin [1 ]
Li, Chao-Jun [1 ]
机构
[1] McGill Univ, Dept Chem, Montreal, PQ, Canada
来源
C-H ACTIVATION | 2010年 / 292卷
关键词
Copper; Ruthenium; Palladium; C-H functionalization; Oxidative coupling; CATALYZED OXIDATIVE CYANATION; MANNICH-TYPE REACTION; PYRIDINE-N-OXIDES; DIRECT ARYLATION; TERTIARY-AMINES; ALLYLIC ALKYLATION; MOLECULAR-OXYGEN; ACTIVATED METHYLENE; HYDROGEN-PEROXIDE; METAL;
D O I
10.1007/128_2009_17
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
New methodologies in cross-coupling reaction using C-H bonds as substrates is of great interest due to the challenges associated with C-H bond activation and the potential to streamline synthesis by the elimination of pre-activation of coupling reagents. In this chapter, recent developments in oxidative cross-coupling reactions will be presented with the focus on the functionalization of sp3 C-H bonds with other C-H bonds
引用
收藏
页码:281 / 302
页数:22
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